Sandstorm events frequently perplex northern China, addressing the people's concern due to subsequent increases in the toxicity and carcinogenicity of PM2.5-bound PAHs (PB-PAHs) in receptor area of sand dust. Here, we enacted a field campaign in a small city between Beijing and Baoding in spring of 2021 covering the sandstorm period (SSP) and non-sandstorm period (NSSP) to examine the sandstorm impacts on chemistries of PB-PAHs. SSP exhibited a slightly high average PAH concentrations of 10.3 ng m-3 than 9.16 ng m-3 in the NSSP. At the same time, the average PM2.5 concentrations obviously increased from 60.7 mu g m-3 to 75.2 mu g m-3. Positive matrix factorization (PMF) analysis manifested that sandstorm largely enhanced the oil leakage and combustion (OLC) fractions from 18.0% in the NSSP to 34.4% in the SSP. Potential source contribution function (PSCF) indicated that OLC partly came from sandstorm origin area-Inner Mongolia. Low diagnostic ratios of FA/(FA + PY) in the SSP also indicated OLC was more important. Accordingly, the largest contributor of incremental lifetime cancer risks (ILCRs) changed from vehicle exhaust (VE) (36.2%) in the NSSP to OLC (34.4%) in the SSP. VE and industrial emission (IE) contributions decreased obviously due to emission control and traffic limitation in the SSP. Coal burning (CB) still held a high contribution to PAHs regardless of the implementation of "coal to gas" law in the sampling area. In addition, sandstorms increased the levels of high molecular weight PAHs (HMW-PAHs) with high toxicity by 4.07%. ILCRs for adults and children increased from 3.90 x 10-7 to 4.74 x 10-7 and from 2.41 x 10-7to 2.93 x 10-7, respectively, in the SSP, which should be more concerned.
基金:
Beijing Natural Science Foundation [8212034]; Natura Science Foundation of Hebei Province [B2020502006, B2020502007]; Science and Technology Projects of Baoding [2141ZF321]; Fundamental Research Funds for the Central Universities [2020MS125]
第一作者机构:[1]North China Elect Power Univ, Dept Environm Sci & Engn, Hebei Key Lab Power Plant Flue Gas Multipollutants, Baoding 071003, Peoples R China[2]North China Elect Power Univ, Coll Environm Sci & Engn, MOE Key Lab Resources & Environm Syst Optimizat, Beijing 102206, Peoples R China
通讯作者:
通讯机构:[1]North China Elect Power Univ, Dept Environm Sci & Engn, Hebei Key Lab Power Plant Flue Gas Multipollutants, Baoding 071003, Peoples R China[2]North China Elect Power Univ, Coll Environm Sci & Engn, MOE Key Lab Resources & Environm Syst Optimizat, Beijing 102206, Peoples R China
推荐引用方式(GB/T 7714):
Li Zhiyong,Zhai Zhen,Liu Jixiang,et al.Impacts of Sandstorms on Chemistries of Ambient PAHs in a Small City in North China[J].AEROSOL AND AIR QUALITY RESEARCH.2023,23(4):doi:10.4209/aaqr.220460.
APA:
Li, Zhiyong,Zhai, Zhen,Liu, Jixiang,Chen, Lan,Ren, Zhuangzhuang...&Guo, Songtao.(2023).Impacts of Sandstorms on Chemistries of Ambient PAHs in a Small City in North China.AEROSOL AND AIR QUALITY RESEARCH,23,(4)
MLA:
Li, Zhiyong,et al."Impacts of Sandstorms on Chemistries of Ambient PAHs in a Small City in North China".AEROSOL AND AIR QUALITY RESEARCH 23..4(2023)