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Impacts of Sandstorms on Chemistries of Ambient PAHs in a Small City in North China

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机构: [1]North China Elect Power Univ, Dept Environm Sci & Engn, Hebei Key Lab Power Plant Flue Gas Multipollutants, Baoding 071003, Peoples R China [2]North China Elect Power Univ, Coll Environm Sci & Engn, MOE Key Lab Resources & Environm Syst Optimizat, Beijing 102206, Peoples R China [3]Hebei Univ, Affiliated Hosp, Dept Pediat, Baoding 071000, Peoples R China [4]BBMG Liushui Environm Protect Technol Co Ltd, Beijing 102400, Peoples R China
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关键词: PM2 5 PAHs Sandstorm Source apportionment Exposure risk

摘要:
Sandstorm events frequently perplex northern China, addressing the people's concern due to subsequent increases in the toxicity and carcinogenicity of PM2.5-bound PAHs (PB-PAHs) in receptor area of sand dust. Here, we enacted a field campaign in a small city between Beijing and Baoding in spring of 2021 covering the sandstorm period (SSP) and non-sandstorm period (NSSP) to examine the sandstorm impacts on chemistries of PB-PAHs. SSP exhibited a slightly high average PAH concentrations of 10.3 ng m-3 than 9.16 ng m-3 in the NSSP. At the same time, the average PM2.5 concentrations obviously increased from 60.7 mu g m-3 to 75.2 mu g m-3. Positive matrix factorization (PMF) analysis manifested that sandstorm largely enhanced the oil leakage and combustion (OLC) fractions from 18.0% in the NSSP to 34.4% in the SSP. Potential source contribution function (PSCF) indicated that OLC partly came from sandstorm origin area-Inner Mongolia. Low diagnostic ratios of FA/(FA + PY) in the SSP also indicated OLC was more important. Accordingly, the largest contributor of incremental lifetime cancer risks (ILCRs) changed from vehicle exhaust (VE) (36.2%) in the NSSP to OLC (34.4%) in the SSP. VE and industrial emission (IE) contributions decreased obviously due to emission control and traffic limitation in the SSP. Coal burning (CB) still held a high contribution to PAHs regardless of the implementation of "coal to gas" law in the sampling area. In addition, sandstorms increased the levels of high molecular weight PAHs (HMW-PAHs) with high toxicity by 4.07%. ILCRs for adults and children increased from 3.90 x 10-7 to 4.74 x 10-7 and from 2.41 x 10-7to 2.93 x 10-7, respectively, in the SSP, which should be more concerned.

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出版当年[2025]版:
大类 | 4 区 环境科学与生态学
小类 | 4 区 环境科学
最新[2025]版:
大类 | 4 区 环境科学与生态学
小类 | 4 区 环境科学
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出版当年[2023]版:
Q3 ENVIRONMENTAL SCIENCES
最新[2023]版:
Q3 ENVIRONMENTAL SCIENCES

影响因子: 最新[2023版] 最新五年平均 出版当年[2023版] 出版当年五年平均 出版前一年[2022版]

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第一作者机构: [1]North China Elect Power Univ, Dept Environm Sci & Engn, Hebei Key Lab Power Plant Flue Gas Multipollutants, Baoding 071003, Peoples R China [2]North China Elect Power Univ, Coll Environm Sci & Engn, MOE Key Lab Resources & Environm Syst Optimizat, Beijing 102206, Peoples R China
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通讯机构: [1]North China Elect Power Univ, Dept Environm Sci & Engn, Hebei Key Lab Power Plant Flue Gas Multipollutants, Baoding 071003, Peoples R China [2]North China Elect Power Univ, Coll Environm Sci & Engn, MOE Key Lab Resources & Environm Syst Optimizat, Beijing 102206, Peoples R China
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