A series of novel cellulose-based hybrid hydrogels were prepared through cellulose and fluorescer Tb3+ doped Y4Si2O7N2 (YT) in NaOH/urea aqueous solution using epichlorohydrin (ECH) as a cross-linker. The structure and properties were characterized by wide-angle X-ray diffraction (XRD), scanning electron microscopy (SEM), FT-IR and fluorescence spectroscopy, as well as by swelling ratio measurements and compression tests. The results revealed that the green fluorescence intensity of the cellulose-based hybrid hydrogels became stronger with an increase of YT contents. The hybrid hydrogels exhibited homogeneous porous structures and the YT particles were tightly embedded in the macroporous cellulose matrix. When the content of YT particles was 0.02 g, the cellulose-based hybrid hydrogels (YTCH3) exhibited stronger fluorescence intensity, higher compressive strength and modulus, and lower swelling ratio.
基金：
National Natural Science Foundation of China (NSFC) [21201053, 51607054]; Hebei Province Natural Science Foundation [F2014201078, A2015201050]; Hebei Province Department of Education (Key Project) [ZD2016055]; Outstanding Youth Fund of Hebei University [2015JQ02]; Post-graduate's Innovation Project of Hebei University [X2016065, X2016066]; Second Batch of Young Talent of Hebei Province
第一作者机构：[1]Hebei Univ, Coll Phys Sci & Technol, Baoding 071002, Peoples R China
通讯作者：
推荐引用方式(GB/T 7714)：
Zhang Wenming,Wang Tianqi,Li Shifeng,et al.NOVEL FLUORESCENT SOFT MATERIAL PREPARED FROM CELLULOSE SOLUTIONS IN ALKALI/UREA AQUEOUS SYSTEM[J].CELLULOSE CHEMISTRY AND TECHNOLOGY.2017,51(9-10):911-917.
APA：
Zhang, Wenming,Wang, Tianqi,Li, Shifeng,Cheng, Kun,Wei, Shuangzhi...&Zhao, Yu.(2017).NOVEL FLUORESCENT SOFT MATERIAL PREPARED FROM CELLULOSE SOLUTIONS IN ALKALI/UREA AQUEOUS SYSTEM.CELLULOSE CHEMISTRY AND TECHNOLOGY,51,(9-10)
MLA：
Zhang, Wenming,et al."NOVEL FLUORESCENT SOFT MATERIAL PREPARED FROM CELLULOSE SOLUTIONS IN ALKALI/UREA AQUEOUS SYSTEM".CELLULOSE CHEMISTRY AND TECHNOLOGY 51..9-10(2017):911-917
