Facile one-pot preparation of an imidazolium embedded C8 hybrid monolith using polyhedral oligomeric silsesquioxane for capillary liquid chromatography
机构：[1]Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, Ministry of Education and Key Laboratory of Pharmaceutical Quality Control of Hebei Province, College of Pharmaceutical Sciences, Hebei University, Baoding 071002, China.[2]Affiliated Hospital of Hebei University, Baoding 071000, China河北大学附属医院
In this study, a novel imidazolium embedded C-8 hybrid monolithic column based on polyhedral oligomeric silsesquioxane (POSS) was developed. With 1-vinyl-3-octylimidazolium bromide (VOI) as functional monomer, POSS-methacryl substituted (POSS-MA) as crosslinker, and azodiisobutyronitrile (AIBN) as thermal initiator, the monolithic column was facilely prepared via a "one-pot" process. The prepared column was characterized by scanning electron microscopy, Fourier transform infrared spectrometry, thermogravimetric analysis, and elemental analysis, respectively. Due to the introduction of VOI to the POSS-based monolith, the column efficiency reached 124 000 theoretical plates per m for separation of alkylbenzenes, outperforming the previously reported pentafluorobenzyl imidazolium bromide modified POSS hybrid monolithic column. Furthermore, high-efficiency separation of polycyclic aromatic hydrocarbons, aromatic amines, and even phenolic isomers was also achieved. All these results suggest the potential merits of the prepared hybrid monolithic column for separation of small molecules.
基金：
National Natural Science Foundation of China [21205027]; Natural Science Foundation of Hebei Province [B2015201016]; Young Talent Program in College and University of Hebei Province [BJ2014005]
第一作者机构：[1]Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, Ministry of Education and Key Laboratory of Pharmaceutical Quality Control of Hebei Province, College of Pharmaceutical Sciences, Hebei University, Baoding 071002, China.
通讯作者：
推荐引用方式(GB/T 7714)：
Zhang Niu,Zhang Lu,Qiao Xiaoqiang,et al.Facile one-pot preparation of an imidazolium embedded C8 hybrid monolith using polyhedral oligomeric silsesquioxane for capillary liquid chromatography[J].RSC ADVANCES.2015,5(111):91436-91440.doi:10.1039/c5ra15823k.
APA：
Zhang, Niu,Zhang, Lu,Qiao, Xiaoqiang,Wang, Yongli,Yan, Hongyuan&Bai, Ligai.(2015).Facile one-pot preparation of an imidazolium embedded C8 hybrid monolith using polyhedral oligomeric silsesquioxane for capillary liquid chromatography.RSC ADVANCES,5,(111)
MLA：
Zhang, Niu,et al."Facile one-pot preparation of an imidazolium embedded C8 hybrid monolith using polyhedral oligomeric silsesquioxane for capillary liquid chromatography".RSC ADVANCES 5..111(2015):91436-91440
